In n = 1 RPP, the BA cations interlaced with each other a result of the conversation with apical I atom (shaded as red) of floor PbI6 octahedron, wherever a bigger in-plane octahedral tilt and a small out-of-airplane tilt exist. In the case of n = four RPP, the BA molecules undertake a “head-to-head” configuration to make sure that thei

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